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1 article(s) from Matushkin, Nikolai

Properties of cationic monosubstituted tetraalkylammonium cyclodextrin derivatives – their stability, complexation ability in solution or when deposited on solid anionic surface

Martin Popr,
Sergey K. Filippov,
Nikolai Matushkin,
Juraj Dian and
Jindřich Jindřich

Beilstein J. Org. Chem. 2015, 11, 192–199, doi:10.3762/bjoc.11.20

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Graphical Abstract

Scheme 1: Thermal decomposition of PEMEDA- and PEMPDA-β-CD with the decomposition products as characterized b...

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Figure 1: Decomposition kinetics of PEMEDA- and PEMPDA-β-CD at 50 °C as determined by ¹H NMR thermal experime...

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Scheme 2: Host and guest molecules employed in K_s determination in solution at different pH.

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Figure 2: Stability constants for β-CD with SAL, MEQ and NIA obtained by ITC measurements.

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Figure 3: Stability constants for PEMPDA-β-CD with SAL, MEQ and NIA obtained by ITC measurements.

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Scheme 3: Deposition of PEMPDA-β-CD onto solid surface (Nafion^® 117).

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Figure 4: Deposition kinetics of PEMPDA-β-CD onto Nafion^® 117 as obtained from ELSD detection of the decreasi...

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Scheme 4: Deposition of three model guests into the cavities of immobilized PEMPDA-β-CD.

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Full Research Paper

Published 02 Feb 2015

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